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Sarek is Vulcan's ambassador to the Federation.
STIII: The Federation has a President and a Council.
STV: A joint Klingon-Romulan-Federation "planet of peace" in the Neutral Zone did not work out very well.
STVI: The Klingon Empire and Federation have been at odds for seventy years. Azetbur bitterly describes the Federation as a "homo sapiens only club." The Klingon Empire is led by a High Council, chief among them the Chancellor.

There appears to be a Neutral Zone between the Federation and Klingon Empire as well.